Stan “Big-Hearted” Lee.
Amazing Spider-Man (Vol. 1) #20
Published: c. November, 1964?
Cover Date: January, 1965
“The Coming of the Scorpion!” Or: “Spidey Battles Scorpey!”
Writer: Stan Lee
Artist: Steve Ditko
Inker: Steve Ditko
Letterer: Sam Rosen
I don’t know if “Scorpey” ever caught on.
Probably as much as “Stevey” did.